TA Instruments

75% SID 25% PCHINA-0038f

06/05/2022 12:16:01 p. m.

Sample name	75% SID 25% PCHINA
Sample notes	 
Experiment notes	
Operator	
Sample density	1,000 g/cm^3
Results file name	75% SID 25% PCHINA
Run number	38 
Results directory	C:\Ta\Data\Ar1500\Ar1500\DIEGO ROA
Experiment was run on	06/05/2022 12:16:01 p. m.

Procedure name	Flow procedure
Procedure notes	

Step name	Conditioning Step 1
Step notes	
Perform step	Yes
Initial temperature	25,0 C
Wait for correct temperature	Yes
Do set temperature	Yes
Perform pre-shear	No
Perform equilibration	Yes
Equilibration duration	0:02:00 hh:mm:ss
Wait for zero velocity	No
Purge gas only	No

Step name	Stepped flow step 1
Step notes	
Perform step	Yes
Ramp type	Stepped flow
Start controlled variable	shear rate 1,000E-3 1/s
End controlled variable	shear rate 0,01000 1/s
Ramp mode	log 
Points per decade	3 
Temperature	25,0 C
Wait for temperature	No
Constant time	0:00:10 hh:mm:ss
Average last x seconds	0:00:05 hh:mm:ss
Motor mode	auto 
Integer rotation averaging	No

Step name	Stepped flow step 2
Step notes	
Perform step	Yes
Ramp type	Stepped flow
Start controlled variable	shear rate 0,01000 1/s
End controlled variable	shear rate 0,1000 1/s
Ramp mode	log 
Points per decade	3 
Temperature	25,0 C
Wait for temperature	No
Constant time	0:00:10 hh:mm:ss
Average last x seconds	0:00:05 hh:mm:ss
Motor mode	auto 
Integer rotation averaging	No

Step name	Stepped flow step 3
Step notes	
Perform step	Yes
Ramp type	Stepped flow
Start controlled variable	shear rate 0,1000 1/s
End controlled variable	shear rate 1,000 1/s
Ramp mode	log 
Points per decade	5 
Temperature	25,0 C
Wait for temperature	No
Constant time	0:00:10 hh:mm:ss
Average last x seconds	0:00:05 hh:mm:ss
Motor mode	auto 
Integer rotation averaging	No

Step name	Stepped flow step 4
Step notes	
Perform step	Yes
Ramp type	Stepped flow
Start controlled variable	shear rate 1,000 1/s
End controlled variable	shear rate 100,0 1/s
Ramp mode	log 
Points per decade	8 
Temperature	25,0 C
Wait for temperature	No
Constant time	0:00:10 hh:mm:ss
Average last x seconds	0:00:05 hh:mm:ss
Motor mode	auto 
Integer rotation averaging	No

Step name	Conditioning Step 2
Step notes	
Perform step	Yes
Initial temperature	25,0 C
Wait for correct temperature	Yes
Do set temperature	Yes
Perform pre-shear	Yes
Pre-shear variable	10,00 1/s
Pre-shear duration	0:00:10 hh:mm:ss
Motor mode	auto 
Perform equilibration	Yes
Equilibration duration	0:02:00 hh:mm:ss
Wait for zero velocity	No
Purge gas only	No

Step name	Temperature ramp step 1
Step notes	
Perform step	Yes
Ramp type	Temperature ramp
Start temperature	25,0 C
End temperature	90,0 C
Wait for start temperature	Yes
Ramp rate	10,00 C/min
Delay time	0:00:09 hh:mm:ss
Controlled variable	shear rate 10,00 1/s
Motor mode	auto 

Step name	Temperature ramp step 2
Step notes	
Perform step	Yes
Ramp type	Temperature ramp
Start temperature	90,0 C
End temperature	90,0 C
Wait for start temperature	No
Ramp duration	0:05:00 hh:mm:ss
Delay time	0:00:09 hh:mm:ss
Controlled variable	shear rate 10,00 1/s
Motor mode	auto 

Step name	Temperature ramp step 3
Step notes	
Perform step	Yes
Ramp type	Temperature ramp
Start temperature	90,0 C
End temperature	25,0 C
Wait for start temperature	No
Ramp rate	10,00 C/min
Delay time	0:00:09 hh:mm:ss
Controlled variable	shear rate 10,00 1/s
Motor mode	auto 

Step name	Conditioning Step 3
Step notes	
Perform step	Yes
Initial temperature	25,0 C
Wait for correct temperature	Yes
Do set temperature	Yes
Perform pre-shear	Yes
Pre-shear variable	1,000 1/s
Pre-shear duration	0:00:10 hh:mm:ss
Motor mode	auto 
Perform equilibration	Yes
Equilibration duration	0:02:00 hh:mm:ss
Wait for zero velocity	No
Purge gas only	No

Step name	Stepped flow step 5
Step notes	
Perform step	Yes
Ramp type	Stepped flow
Start controlled variable	shear rate 1,000E-3 1/s
End controlled variable	shear rate 0,01000 1/s
Ramp mode	log 
Points per decade	3 
Temperature	25,0 C
Wait for temperature	No
Constant time	0:00:10 hh:mm:ss
Average last x seconds	0:00:05 hh:mm:ss
Motor mode	auto 
Integer rotation averaging	No

Step name	Stepped flow step 6
Step notes	
Perform step	Yes
Ramp type	Stepped flow
Start controlled variable	shear rate 0,01000 1/s
End controlled variable	shear rate 0,1000 1/s
Ramp mode	log 
Points per decade	3 
Temperature	25,0 C
Wait for temperature	No
Constant time	0:00:10 hh:mm:ss
Average last x seconds	0:00:05 hh:mm:ss
Motor mode	auto 
Integer rotation averaging	No

Step name	Stepped flow step 7
Step notes	
Perform step	Yes
Ramp type	Stepped flow
Start controlled variable	shear rate 0,1000 1/s
End controlled variable	shear rate 1,000 1/s
Ramp mode	log 
Points per decade	5 
Temperature	25,0 C
Wait for temperature	No
Constant time	0:00:10 hh:mm:ss
Average last x seconds	0:00:05 hh:mm:ss
Motor mode	auto 
Integer rotation averaging	No

Step name	Stepped flow step 8
Step notes	
Perform step	Yes
Ramp type	Stepped flow
Start controlled variable	shear rate 1,000 1/s
End controlled variable	shear rate 100,0 1/s
Ramp mode	log 
Points per decade	8 
Temperature	25,0 C
Wait for temperature	No
Constant time	0:00:10 hh:mm:ss
Average last x seconds	0:00:05 hh:mm:ss
Motor mode	auto 
Integer rotation averaging	No

Step name	Post-Experiment Step
Step notes	
Perform step	Yes
Do set temperature	No
Set temperature system idle	No

Geometry name	Starch cell
Geometry notes	Starch cell
Geometry material	High temperature
gap	5500 micro m
Calibration factor	10800 
Gap offset	0 micro m
Geometry inertia	2,226 micro N.m.s^2
Shear rate factor	1,000 
Shear stress factor	10800 1/m^3
Measurement system factor	10800 1/m^3
Fluid density factor	1,000E-15 m^5
Normal force factor	1,000 1/m^2
Backoff distance	1,25E5 micro m

Gap zero mode	Standard
Sample compression	none 
Compression distance	1000,0 micro m
Compression velocity	100,0 micro m/s
Fine velocity	1000,0 micro m/s
Coarse velocity	3000,0 micro m/s
Other velocity	3000,0 micro m/s
Current temperature system	Starch cell
Temperature control	Enabled 
Purge gas only	No
Temperature calibration	Peltier plate - 0 micro m/C
	Water bath - 0 micro m/C
	Torsion oven - plate - 0 micro m/C
	Torsion oven - solid sample - 0 micro m/C
	Peltier concentric cylinders - 0 micro m/C
	None - 0 micro m/C
	Stress relaxation - 0 micro m/C
	Current temperature system - 0 micro m/C
Cooling water temperature	5,0 C
Cooling water range	15,0 C
Bearing friction correction	Yes
Bearing friction	1,222 micro N.m/(rad/s)
Bearing offset	0 micro N.m
Temperature system span and offset	Peltier plate - span 1,0000 , offset 0 C
	Water bath - span 1,0000 , offset 0 C
	Torsion oven - plate - span 1,0000 , offset 0 C
	Torsion oven - solid sample - span 1,0000 , offset 0 C
	Peltier concentric cylinders - span 1,0000 , offset 0 C
	None - span 1,0000 , offset 0 C
	Stress relaxation - span 1,0000 , offset 0 C
	Current temperature system - span 1,0000 , offset 0 C
Bearing mapping type	fast 
Number of mapping iterations	1
Instrument type (MType)	AR1500ex
Firmware version	  8.29  27/10/09
Configuration version (CnfVer)	301
Parameter version (PrmVer)	301
PCB Number	*NOT_SET*
IP address	172.23.191.2
Software version	V5.8.2
Windows version	Windows XP 6.2
Instrument inertia	15,97 micro N.m.s^2
Auto increment run number	Yes
Prompt for file name at start of run	Yes
Auto save results file	Yes
Results file storage	Consecutive steps of same type to 1 file 
Temperature tolerance	0,2 C
Temperature duration	0:00:10 hh:mm:ss
Wait for temperature even if OK	Yes
Gap tolerance	4 micro m
Gap duration	0:00:02 hh:mm:ss
Override wait for gap	No
Velocity tolerance	0,1000 rad/s
Zero speed after pre-shear	Leave as is 
Zero normal force before run	No
Zero timer before run	Before pre-shear 
Non-equilibrium minimum velocity	3,000E-4 rad/s
Zero strain at the start of each flow step	Yes
Inertia correction	No
Collect negative shear rate data if stress is positive	Yes
Collect all points	No
Display flow point graph during run	Yes
Store flow point graph with results	Yes
Store images to the results for flow steps	No
Creep zero displacement	Yes
Store images to the results for creep steps	No
Standard creep image store frequency	10 s
Repeated creep image store frequency in repeats	10 
Display oscillation waveform graph during run	Yes
Store oscillation waveform graph with results	Yes
Display strain control tries during run	Yes
Store strain control tries with results	Yes
Store images to the results for oscillation steps	No
Stress relaxation zero displacement	Yes
Store images to the results for stress relaxation steps	No
Flow torque limit	10,00 micro N.m
Flow velocity limit	1,000E-3 rad/s
Oscillation torque limit	5,00 micro N.m
Oscillation displacement limit	1,00E-5 rad
Oscillation raw phase limit	170,0 degrees
Oscillation minimum normal force limit	0 N
Oscillation maximum normal force limit	0 N
Flow velocity tolerance	5,00 %
Oscillation torque tolerance	1,00 %
Oscillation displacement tolerance	5,00 %
Oscillation velocity tolerance	5,00 %
Temperature tolerance	1,0 C

Stepped flow step 1

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

3,600E-3	9,426E-4	3,819	9,9530	25,0	0
0,06664	2,152E-3	30,97	20,000	25,0	0
0,1992	4,640E-3	42,94	30,046	25,0	0
0,4644	9,998E-3	46,45	40,140	25,0	0

Stepped flow step 2

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

0,7285	9,997E-3	72,87	9,9370	25,0	0
1,303	0,02154	60,48	19,984	25,0	0
2,282	0,04641	49,18	30,015	25,0	0
3,111	0,1000	31,11	40,046	25,0	0
2,545	0,1000	25,45	50,093	25,0	0

Stepped flow step 3

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

2,434	0,09999	24,34	9,9840	25,0	0
2,169	0,1585	13,69	20,047	25,0	0
1,831	0,2512	7,290	30,078	25,0	0
1,469	0,3982	3,690	40,156	25,0	0
1,067	0,6309	1,692	50,218	25,0	0
0,6894	1,000	0,6894	60,312	25,0	0

Stepped flow step 4

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

0,5716	1,000	0,5717	9,9530	25,0	0
0,5306	1,334	0,3979	20,000	25,0	0
0,4524	1,778	0,2544	30,078	25,0	0
0,4044	2,371	0,1705	40,125	25,0	0
0,3708	3,162	0,1173	50,218	25,0	0
0,3534	4,217	0,08380	60,281	25,0	0
0,3487	5,623	0,06201	70,312	25,0	0
0,3490	7,499	0,04654	80,343	25,0	0
0,4691	10,00	0,04691	90,375	25,0	0
0,7205	13,34	0,05403	100,44	25,0	0
1,185	17,78	0,06665	110,47	25,0	0
1,763	23,71	0,07436	120,58	25,0	0
2,613	31,62	0,08262	130,67	25,0	0
3,659	42,17	0,08678	140,70	25,0	0
5,469	56,23	0,09724	150,76	25,0	0
7,754	74,99	0,1034	160,83	25,0	0
10,46	100,0	0,1046	170,91	25,0	0

Temperature ramp step 1

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

0,5053	10,00	0,05053	9,0160	25,0	0
0,4989	10,00	0,04989	18,008	25,6	0
0,4925	10,00	0,04925	27,020	26,7	0
0,4870	10,00	0,04870	36,016	28,3	0
0,4746	10,00	0,04746	45,008	29,9	0
0,4669	10,00	0,04669	54,020	31,6	0
0,4600	10,00	0,04600	63,012	33,2	0
0,4496	10,00	0,04496	72,016	34,9	0
0,4443	10,00	0,04442	81,012	36,5	0
0,4379	10,00	0,04379	90,024	38,1	0
0,4345	10,00	0,04345	99,020	39,7	0
0,4326	10,00	0,04326	108,02	41,3	0
0,4322	10,00	0,04322	117,01	42,8	0
0,4298	10,00	0,04298	126,00	44,4	0
0,4316	10,00	0,04315	135,02	45,8	0
0,4327	10,00	0,04326	144,00	47,4	0
0,4385	10,00	0,04385	153,01	48,8	0
0,4423	10,00	0,04423	162,02	50,3	0
0,4469	10,00	0,04469	171,01	51,9	0
0,4540	10,00	0,04540	180,02	53,4	0
0,4592	10,00	0,04592	189,02	54,9	0
0,4640	10,00	0,04640	198,02	56,4	0
0,4637	10,00	0,04637	207,02	57,8	0
0,4616	10,00	0,04616	216,01	59,3	0
0,4673	10,00	0,04673	225,02	60,8	0
0,4737	10,00	0,04737	234,01	62,4	0
0,4748	10,00	0,04748	243,01	63,9	0
0,4824	10,00	0,04824	252,01	65,4	0
0,4850	10,00	0,04850	261,02	66,9	0
0,4983	10,00	0,04983	270,02	68,5	0
0,5100	10,00	0,05100	279,00	70,0	0
0,5424	10,00	0,05424	288,02	71,4	0
0,6078	9,999	0,06078	297,01	73,0	0
0,7266	10,00	0,07266	306,02	74,4	0
0,9935	10,00	0,09935	315,01	75,9	0
1,567	9,999	0,1567	324,02	77,3	0
2,290	10,00	0,2290	333,01	78,8	0
2,978	10,00	0,2979	342,01	80,2	0
3,575	10,00	0,3575	351,01	81,6	0
3,841	10,00	0,3841	360,02	83,1	0
3,842	10,00	0,3842	369,01	84,7	0

Temperature ramp step 2

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

3,913	10,00	0,3913	8,9920	86,6	0
4,487	10,00	0,4487	18,004	89,0	0
5,781	9,999	0,5781	26,996	90,4	0
8,284	10,00	0,8282	35,988	90,7	0
11,30	10,01	1,129	44,992	90,8	0
11,72	9,995	1,172	53,992	91,3	0
8,512	9,995	0,8517	63,000	91,8	0
6,306	9,991	0,6311	72,000	90,1	0
5,080	9,995	0,5083	80,988	89,0	0
4,708	10,00	0,4707	89,992	89,3	0
4,843	10,01	0,4839	99,012	89,8	0
4,713	10,01	0,4708	108,00	90,1	0
4,688	9,990	0,4693	117,00	90,2	0
4,509	10,00	0,4509	125,98	90,4	0
4,328	10,00	0,4328	135,00	90,6	0
4,186	9,998	0,4187	144,00	90,7	0
3,996	10,00	0,3997	153,00	90,6	0
3,783	10,00	0,3783	161,98	90,5	0
3,668	10,00	0,3668	170,98	90,3	0
3,596	10,00	0,3596	179,99	90,2	0
3,554	10,00	0,3554	189,00	90,1	0
3,497	10,00	0,3497	198,00	90,1	0
3,456	10,00	0,3456	206,99	90,1	0
3,413	10,00	0,3413	216,00	90,1	0
3,389	10,00	0,3389	225,00	90,0	0
3,335	10,00	0,3335	233,98	90,0	0
3,292	10,00	0,3292	242,99	90,0	0
3,272	9,999	0,3273	251,98	90,0	0
3,254	10,00	0,3254	261,00	90,0	0
3,220	10,00	0,3220	270,00	90,0	0
3,200	10,00	0,3200	278,98	90,0	0

Temperature ramp step 3

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

3,169	10,00	0,3169	9,0000	90,0	0
3,136	10,00	0,3136	18,008	89,3	0
3,101	10,00	0,3101	27,016	86,4	0
3,084	10,00	0,3084	36,008	85,5	0
3,072	10,00	0,3072	45,008	84,8	0
3,082	10,00	0,3082	54,012	83,5	0
3,124	10,00	0,3124	63,012	81,3	0
3,165	10,00	0,3165	72,000	80,1	0
3,173	10,00	0,3173	81,008	79,0	0
3,247	10,00	0,3247	90,012	76,5	0
3,269	10,00	0,3269	98,996	75,5	0
3,316	10,00	0,3316	108,00	74,2	0
3,388	10,00	0,3388	117,01	72,0	0
3,417	10,00	0,3417	126,01	71,2	0
3,518	10,00	0,3518	135,02	69,1	0
3,565	10,00	0,3565	144,02	67,7	0
3,634	10,00	0,3634	153,01	66,5	0
3,720	10,00	0,3720	162,02	64,5	0
3,792	10,00	0,3792	171,01	63,6	0
3,891	10,00	0,3891	180,00	61,5	0
3,947	10,00	0,3947	189,02	60,4	0
4,064	10,00	0,4064	198,00	58,7	0
4,166	10,00	0,4166	207,01	57,1	0
4,262	10,00	0,4262	216,01	56,0	0
4,396	10,00	0,4396	225,01	54,1	0
4,497	10,00	0,4497	234,01	53,0	0
4,660	10,00	0,4660	243,00	51,0	0
4,799	10,00	0,4799	252,00	49,9	0
4,980	10,00	0,4980	261,01	48,1	0
5,133	10,00	0,5132	270,01	46,7	0
5,315	10,00	0,5315	279,01	45,2	0
5,513	10,00	0,5513	288,02	43,7	0
5,679	10,00	0,5679	297,00	42,2	0
5,899	10,00	0,5900	306,01	40,7	0
6,080	10,00	0,6080	315,01	39,2	0
6,272	10,00	0,6272	324,02	37,7	0
6,491	10,00	0,6491	333,02	36,2	0
6,697	10,00	0,6697	342,01	34,8	0
6,953	10,00	0,6954	351,00	33,2	0
7,184	10,00	0,7184	360,00	31,8	0
7,417	10,00	0,7417	369,01	30,3	0

Stepped flow step 5

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

0,1082	1,001E-3	108,0	9,9070	25,0	0
0,2109	2,153E-3	97,95	19,969	25,0	0
0,3661	4,640E-3	78,92	30,000	24,9	0
0,6773	9,999E-3	67,74	40,110	25,0	0

Stepped flow step 6

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

0,8527	9,999E-3	85,28	9,9690	25,0	0
1,156	0,02154	53,63	20,000	25,0	0
1,478	0,04642	31,84	30,063	24,9	0
1,826	0,1000	18,27	40,125	25,0	0
1,823	0,1000	18,23	50,219	25,1	0

Stepped flow step 7

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

1,842	0,1000	18,42	9,9380	25,0	0
2,049	0,1585	12,93	19,985	24,9	0
2,215	0,2512	8,817	30,063	25,0	0
2,499	0,3981	6,277	40,125	25,1	0
2,860	0,6310	4,532	50,156	25,0	0
3,312	1,000	3,312	60,281	24,9	0

Stepped flow step 8

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

3,293	1,000	3,292	9,9380	25,0	0
3,617	1,334	2,713	19,984	25,0	0
4,029	1,778	2,266	30,109	25,0	0
4,553	2,371	1,920	40,188	25,0	0
5,178	3,162	1,637	50,250	25,0	0
5,928	4,217	1,406	60,328	25,0	0
6,834	5,623	1,215	70,391	25,0	0
7,911	7,499	1,055	80,453	25,0	0
9,176	10,00	0,9176	90,484	25,0	0
10,72	13,34	0,8037	100,53	25,0	0
12,56	17,78	0,7061	110,64	25,0	0
14,79	23,71	0,6236	120,73	25,0	0
17,42	31,62	0,5507	130,78	24,9	0
20,16	42,17	0,4782	140,84	25,0	0
23,11	56,23	0,4110	150,94	25,0	0
25,35	74,99	0,3381	161,05	25,0	0
32,72	100,0	0,3272	171,09	25,0	0

